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ammonium bifluoride : ウィキペディア英語版
ammonium bifluoride

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Ammonium hydrogen fluoride is the inorganic compound with the formula NH4HF2 or NH4F·HF. It is produced from ammonia and hydrogen fluoride. This colourless salt is a glass-etchant and an intermediate in a once-contemplated route to hydrofluoric acid.
== Structure ==
Ammonium bifluoride, as its name indicates, contains a bifluoride, or hydrogen(difluoride) anion: HF2. This centrosymmetric triatomic anion features the strongest known hydrogen bond, with a FH length of 114 pm. and a bond energy greater than 155 kJ mol−1.〔Emsley, J. (1980) ''Very strong hydrogen bonds'', Chemical Society Reviews, 9, 91–124. 〕
In solid ()(), each ammonium cation is surrounded by four fluoride centers in a tetrahedron, with hydrogen-fluorine hydrogen bonds present between the hydrogen atoms of the ammonium ion and the fluorine atoms. Solutions contain tetrahedral ()+ cations and linear () anions.

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